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41.
42.
David M. Bernstein Michael T. Kleinman Theo. J. Kneip Tai L. Chan Morton Lippmann 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1069-1072
A size selective particle sampler has been developed for continuous sampling of the urban aerosol over periods ranging from hours to weeks, providing relatively large sample weights. The system, which is now operating in New York City, uses a parallel array of two-stage samplers. The cyclones used as the first stage collectors have 50% particle retention at 3.5,2.5,1.5 and 0.5 µm aerodynamic diameter, respectively. Undersize particles which pass through the cyclones are captured on glass fiber filters. Equal intake velocities are assured by using flow equalizers on the inlets to the cyclones. Accurate control of the flow through the cyclones is obtained by the use of an integrated circuit pressure transducer in conjunction with a specially designed feedback control circuit. The collection efficiencies of the cyclone were calibrated using monodisperse ferric oxide test aerosols tagged with Tc-99m. Mass balances of the par-ticulates collected on the cyclones and filters are obtained for the five sampling stages. Preliminary results show the distributions of the total suspended particulates in New York City to be bimodal. The distributions of lead, copper, and manganese with particle size are also discussed. 相似文献
43.
44.
Florentino B. De la Cruz Jeffrey P. Chanton Morton A. Barlaz 《Waste management (New York, N.Y.)》2013,33(10):2001-2005
Landfills are an anaerobic ecosystem and represent the major disposal alternative for municipal solid waste (MSW) in the U.S. While some fraction of the biogenic carbon, primarily cellulose (Cel) and hemicellulose (H), is converted to carbon dioxide and methane, lignin (L) is essentially recalcitrant. The biogenic carbon that is not mineralized is stored within the landfill. This carbon storage represents a significant component of a landfill carbon balance. The fraction of biogenic carbon that is not reactive in the landfill environment and therefore stored was derived for samples of excavated waste by measurement of the total organic carbon, its biogenic fraction, and the remaining methane potential. The average biogenic carbon content of the excavated samples was 64.6 ± 18.0% (average ± standard deviation), while the average carbon storage factor was 0.09 ± 0.06 g biogenic-C stored per g dry sample or 0.66 ± 0.16 g biogenic-C stored per g biogenic C. 相似文献
45.
Robert T. Cheng John O. Frohliger Morton Corn 《Journal of the Air & Waste Management Association (1995)》2013,63(3):138-141
A major difficulty encountered in laboratory research on the atmospheric interaction of an aerosol-gas system is the unstable nature of the aerosol phase. Previously reported aerosol stabilizing techniques often severely alter the aerosol so that laboratory results cannot be validly extrapolated to the atmospheric environment. A new technique which does not alter the nature of the aerosol is described in this paper. Aerosol particles are deposited on an inert substrate such as Teflon beads. The deposition is carried out in a fluidized-bed to ensure discrete aerosol deposition and to achieve a uniform distribution of aerosol concentration on the supporting beads. Aerosol-gas interactions can be investigated conveniently by exposing these stabilized aerosols to the reacting gases in dynamic or static systems. Laboratory results obtained by using stabilized aerosols may be extrapolated to the atmospheric environment. This aerosol stabilizing technique was incorporated into an investigation of the particulate-catalyzed atmospheric oxidation of sulfur dioxide. Teflon beads with deposited aerosol particles of CuCl2, MnCl2, and NaCI were exposed to 4–42 ppm of sulfur dioxide in a plug flow reactor. The rate of oxidation of sulfur dioxide was found to be influenced by type of catalyst, concentration of catalyst, relative humidity and concentration of sulfur dioxide. The rate of oxidation by sodium chloride particulate was measurable at low to moderate relative humidities (45–60%), but the rate was several times higher when the sodium chloride catalyst particles change from solid form into droplet form at high relative humidities (>80%). 相似文献
46.
Twenty-four fluorochemicals were quantified in landfill leachates recovered from municipal refuse using an analytical method based on solid-phase extraction, dispersive-carbon sorbent cleanup, and liquid chromatography/tandem mass spectrometry. The method was applied to six landfill leachates from four locations in the US as well as to a leachate generated by a laboratory bioreactor containing residential refuse. All seven leachates had the common characteristic that short-chain (C4-C7) carboxylates or sulfonates were greater in abundance than their respective longer-chain homologs (?C8). Perfluoroalkyl carboxylates were the most abundant (67 ± 4% on a nanomolar (nM) basis) fluorochemicals measured in leachates; concentrations of individual carboxylates reaching levels up to 2800 ng L−1. Perfluoroalkyl sulfonates were the next most abundant class (22 ± 2%) on a nM basis; their abundances in each of the seven leachates derived from municipal refuse were greater for the shorter-chain homologs (C4 and C6) compared to longer-chain homologs (C8 and C10). Perfluorobutane sulfonate concentrations were as high as 2300 ng L−1. Sulfonamide derivatives composed 8 ± 2.1% (nM basis) of the fluorochemicals in landfill leachates with methyl (C4 and C8) and ethyl (C8) sulfonamide acetic acids being the most abundant. Fluorotelomer sulfonates (6:2 and 8:2) composed 2.4 ± 1.3% (nM basis) of the fluorochemicals detected and were present in all leachates. 相似文献
47.
R. Michael Erwin David F. Brinker Bryan D. Watts Gary R. Costanzo David D. Morton 《Journal of Coastal Conservation》2011,15(1):51-60
Like many resources in the Chesapeake Bay region of the U.S., many waterbird nesting populations have suffered over the past
three to four decades. In this study, historic information for the entire Bay and recent results from the Tangier Sound region
were evaluated to illustrate patterns of island erosion and habitat loss for 19 breeding species of waterbirds. Aerial imagery
and field data collected in the nesting season were the primary sources of data. From 1993/1994 to 2007/2008, a group of 15
islands in Tangier Sound, Virginia were reduced by 21% in area, as most of their small dunes and associated vegetation and
forest cover were lost to increased washovers. Concurrently, nesting American black ducks (Anas rubripes) declined by 66% , wading birds (herons-egrets) by 51%, gulls by 72%, common terns (Sterna hirundo) by 96% and black skimmers (Rynchops niger) by about 70% in this complex. The declines noted at the larger Bay-wide scale suggest that this study area maybe symptomatic
of a systemic limitation of nesting habitat for these species. The island losses noted in the Chesapeake have also been noted
in other Atlantic U.S. coastal states. Stabilization and/or restoration of at least some of the rapidly eroding islands at
key coastal areas are critical to help sustain waterbird communities. 相似文献
48.
James R. Benson Morton Corn 《Journal of the Air & Waste Management Association (1995)》2013,63(4):340-348
Cost data were analyzed from thirty steam power plant units utilizing electrostatic precipitators with or without mechanical centrifugal collectors. Operational, maintenance, and total costs for the years 1969, 1970, and 1971 were expressed in 1972 dollars as $/cfm-yr and $/cfm-yr-efficiency. The latter parameter is a new one which normalizes the cost of air cleaning by accounting for the amount of particulate matter collected. Large differences in the costs of air cleaning were found between plants and even between units operating in the same plant. Maintenance costs appeared to be the main contributor to large total cost differences, but improved, more specific accounting procedures are required to focus more closely on the reasons for cost differences. 相似文献
49.
Estimating Annual Groundwater Evapotranspiration from Phreatophytes in the Great Basin Using Landsat and Flux Tower Measurements 总被引:1,自引:0,他引:1
Jordan P. Beamer Justin L. Huntington Charles G. Morton Greg M. Pohll 《Journal of the American Water Resources Association》2013,49(3):518-533
Escalating concerns about water supplies in the Great Basin have prompted numerous water budget studies focused on groundwater recharge and discharge. For many hydrographic areas (HAs) in the Great Basin, most of the recharge is discharged by bare soil evaporation and evapotranspiration (ET) from phreatophyte vegetation. Estimating recharge from precipitation in a given HA is difficult and often has significant uncertainty, therefore it is often quantified by estimating the natural discharge. As such, remote sensing applications for spatially distributing flux tower estimates of ET and groundwater ET (ETg) across phreatophyte areas are becoming more common. We build on previous studies and develop a transferable empirical relationship with uncertainty bounds between flux tower estimates of ET and a remotely sensed vegetation index, Enhanced Vegetation Index (EVI). Energy balance‐corrected ET measured from 40 flux tower site‐year combinations in the Great Basin was statistically correlated with EVI derived from Landsat imagery (r2 = 0.97). Application of the relationship to estimate mean‐annual ETg from four HAs in western and eastern Nevada is highlighted and results are compared with previous estimates. Uncertainty bounds about the estimated mean ETg allow investigators to evaluate if independent groundwater discharge estimates are “believable” and will ultimately assist local, state, and federal agencies to evaluate expert witness reports of ETg, along with providing new first‐order estimates of ETg. 相似文献
50.
Thwaites RH Ashmore MR Morton AJ Pakeman RJ 《Environmental pollution (Barking, Essex : 1987)》2006,144(2):500-509
Although ozone has been shown to reduce the growth of individual species and to alter the composition of simple species mixtures, there is little understanding of its long-term effects on species dynamics and composition in real communities. Intact turfs of calcareous grassland were exposed to four different ozone regimes in open-top chambers over three consecutive summers. Treatments provided a mean seasonal AOT40 ranging from approximately zero to 15 ppm h. Cumulative ozone exposure was a significant factor in compositional change, but only explained 4.6% of the variation. The dominant grass species (Festuca rubra) showed a consistent decline in cover in the high ozone treatment over time and the forb Campanula rotundifolia was lost from all three ozone treatments. The frequency of some species (Galium verum and Plantago lanceolata) increased with ozone exposure. Long-term effects of ozone on species composition in chalk grassland may be a function of both the sensitivity of individual species and the response of the dominant species. 相似文献